Key difference allylic vs vinylic carbons functional groups are very important in understanding the different physical and chemical properties of organic molecules the terms allylic and vinyl carbons indicate whether the carbon atom is bonded directly or indirectly to a double bond in a molecule. This book emphasizes that the reaction through vinyl cations is a viable pathway among the multitude of mechanistic routes for vinylic substitution. An allylic carbocation in which an allylic carbon bears the positive charge.
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